extraction molybdenum selective

Pressure Oxidation of Molybdenum Concentrates

Pressure Oxidation of Molybdenum Concentrates By Kyle Gough, Sarah Holmes, ... • The focus was to compare selective alkaline POX for Mo and ... Re extraction is achieved at long reaction times with

Selective extraction of molybdenum from copper concentrate ...

Selective leaching of molybdenum from copper concentrate by air oxidation was investigated in alkaline solution. • The leaching behaviors of Cu and Mo phase were predicted by Eh-pH diagrams of Mo-S-H 2 O and Cu–Fe–S–H 2 O system, respectively.. The oxidation mechanisms of sulfides in the copper concentrate were illustrated by methods of XRD and SEM-EDS.

Molybdenum - Wikipedia

Molybdenum-98 is the most abundant isotope, comprising 24.14% of all molybdenum. Molybdenum-100 has a half-life of about 10 19 y and undergoes double beta decay into ruthenium-100. Molybdenum isotopes with mass numbers from 111 to 117 all have half-lives of approximately 150 ns.

Extraction and selective stripping of molybdenum(VI) and ...

Nevertheless, no information has been found regarding the simulta- neous selective extraction and separation of molybdenum(VI) and vanadium(IV) from an aqueous acidic sulfate solution containing aluminum(Ill), cobalt(II), nickel(II) and iron(Ill) in addition to molybdenum(VI) and vanadium(IV) using LIX 63 as an extractant.

SPECTROPHOTOMETRIC DETERMINATION OF MOLYBDENUM IN ...

spectrophotometric determination of molybdenum in environmental and food samples using solvent extraction html full text. spectrophotometric determination of molybdenum in environmental and food samples using solvent extraction. k. a. kuliev *, n. a. verdizadeh, g. s. suleymanova, r. …

Leaching and recovery of molybdenum, nickel and cobalt ...

Leaching and recovery of molybdenum, nickel and cobalt from metals recycling plants mineral sludges Mirjana Vemic To cite this version: Mirjana Vemic. Leaching and recovery of molybdenum, nickel and cobalt from metals recycling plants ... Solvent extraction 33 2.5.5. Evaluation of recovery of molybdenum from spent catalysts 35 2.6. Conclusion ...

Selective extraction and deep removal of tungsten from ...

Request PDF on ResearchGate | Selective extraction and deep removal of tungsten from sodium molybdate solution by primary amine N1923 | Selectively …

US4026988A - Selective extraction of molybdenum from ...

Molybdenum is selectively extracted from an aqueous solution containing various other metal values, e.g. copper, arsenic, iron, bismuth, antimony, tin, and lead in addition to molybdenum. The molybdenum-bearing solution is adjusted to a pH of about 2.0 or less, and, then, intimately contacted with an organic extracting solution containing an alpha-hydroxy oxime.

Method of extraction of molybdenum from molybdenum ...

FIELD: petrochemical industry; methods of the selective extraction of molybdenum from the solutions containing molybdenum and vanadium. SUBSTANCE: the invention is pertaining to the method of the selective extraction of molybdenum from the liquid mixtures, in which molybdenum is present with vanadium at the amount of molybdenum exceeding (200) mg/l.

Chemical Treatment to Recover Molybdenum and …

Chemical Treatment to Recover Molybdenum and ... Extraction of Vanadium and Molybdenum . ... Figure 3 reveals that at 20 wt% of caustic soda content in the feed mixture, molybdenum recovery reaches 91.0% and about 97% of the V present in the spent catalyst was ex- tracted. An increase in caustic soda content produces a

Separation of Simulated Mixed Mo(VI) and V(V) From HNO3 ...

Equilibrium study was carried out to determine the optimum conditions required for Mo(VI) extraction from HNO3 solutions and subsequently, simulated mixed Mo(VI), and V(V) were extracted from HNO3 (pH = 1.0) and 6.0 mol L−1 HCl solutions with TBP dissolved in n-hexane. The variation of pH (selective extraction) and selective stripping were investigated as methods of separation of Mo(VI) and ...

Structure and properties of molybdenum oxide nitrides as ...

Jul 15, 2011· Structure and properties of molybdenum oxide nitrides as model systems for selective oxidation catalysts. ... Hot gas extraction, however, does not permit to study the nitrogen content of the material in situ under catalysis or oxidation …

US Patent for Selective extraction of molybdenum and ...

Selective extraction of molybdenum and vanadium from spent catalysts by oxidative leaching with sodium aluminate and caustic . May 9, 1986 - Amax Inc. Spent hydrodesulfurization catalysts containing alumina, at least one metal from the group consisting of molybdenum, tungsten and vanadium and at least one metal from the group consisting of ...

A selective extraction-photometric determination of ...

Read "A selective extraction-photometric determination of molybdenum(V) employing N-hydroxy-N-p-chlorophenyl-N′-(2-methyl-4-chlorophenyl)benzamidine hydrochloride in the presence of thiocyanat, Analytical and Bioanalytical Chemistry" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.

Extraction of molybdenum and nickel from carbonaceous ...

PDF | The extraction of molybdenum and nickel from a carbonaceous shale ore was investigated by oxidation roasting, followed by sulphation roasting and water leaching. The results indicated that ...

US4666685A - Selective extraction of molybdenum and ...

Spent hydrodesulfurization catalysts containing alumina, at least one metal from the group consisting of molybdenum, tungsten and vanadium and at least one metal from the group consisting of nickel and cobalt, sulfur, and, usually, residual oil are oxygen pressure leached at a temperature of at least about 400° F. with a base from the group consisting of sodium hydroxide and sodium aluminte ...

A literature review of the recovery of molybdenum and ...

Ammonium salt precipitation is the primary method for the separation of vanadium from molybdenum. Usually after vanadium precipitation, there is a small amount of molybdenum in the NH 4 VO 3 crystal product and 30–100 mg/kg vanadium in the filtrate containing molybdenum (Shi and Wang, 2004).Solvent extraction and ion exchange are thereafter applied to completely separate molybdenum …

Solvent extraction of molybdenum from acidic leach ...

May 30, 2013· A P204 (D2EHPA) diluted with sulfonated kerosene was used for the selective extraction of molybdenum from an acidic Ni–Mo ore leach solution that was reduced using sodium thiosulfate. The results...

Sustainable Extraction and Separation of Rhenium and ...

polymer. In a second part, quantitative and selective stripping of molybdenum directly from the polymer-rich phase after extraction was achieved in one step by addition of quaternary ammonium salts, yielding a molybdenum polyoxometalate of high purity. The selective recovery of molybdenum was optimized with regards to the nature and ...

Durable molybdenum oxide coated solid‐phase ...

The molybdenum oxides coating had a high scratch resistance, which could effectively prevent coating wear and failure. Combined with the high thermal and chemical stability, the service life of the coating was improved and could be used 150 times without a significant reduction in the extraction performance.

SELECTIVE EXTRACTION OF VANADIUM (V) FROM SOLUTIONS ...

Mar 30, 2007· Several separation schemes, involving liquid-liquid extraction procedures, were found to be theoretically feasible in order to separate Vanadium and Molybdenum based on computer simulation of the acid-base properties of these metals, where cationic …

EP2580763A2 - Methods and apparatus for selective gaseous ...

SELECTIVE GASEOUS EXTRACTION OF MOLYBDENUM-99 AND OTHER FISSION . PRODUCT RADIOISOTOPES . I. Field Of The Invention [0001] This application generally relates to apparatus and methods for extracting the isotope Molybdenum-99 and certain other fission product radioisotopes for medical and/or commercial purposes in a timely, economical manner and ...

Highly enhanced selectivity for the ... - SpringerLink

Jun 10, 2015· An effective method based on magnetic solid-phase extraction for the selective recovery of rhenium and molybdenum has been developed using diethylamine-functionalized magnetic CuFe 2 O 4 (NH 2 @CuFe 2 O 4) as adsorbents. Various experimental parameters that could affect the extraction efficiency had been investigated in detail.

Selective recovery of molybdenum(vi) - russianpatents.com

Method for the selective extraction of molybdenum (VI) from solutions of cations of heavy metals refers to the extraction of substances with the use of sorbents and can be used in ferrous and nonferrous metallurgy, as well as for the treatment of industrial and domestic wastewater and recycling of non-ferrous metals containing molybdenum (VI).

Co-extraction and selective stripping of copper (II) and ...

Jan 01, 2001· The extraction of both metals is sensitive to equilibrium pH; however, molybdenum is extracted preferably to copper at acidic pH values. For aqueous phases containing both metals, conditions were established for the co-extraction, selective stripping of copper and molybdenum and NH 3 removal from the stripped organic solution.

Solvent extraction of rhenium from molybdenum in alkaline ...

The technology of selective extraction of rhenium from alkaline solutions containing rhenium and molybdenum by solvent extraction using a mixture of tributyl phosphate and triotylamine as ...

Selective extraction of molybdenum from acidic leach ...

May 31, 1977· Molybdenum species which are present in the aqueous solution in a lower oxidation state, e.g. 2 or 3, tend to form emulsion products at the interface between the aqueous and organic phases, thereby reducing the efficiency of the extraction. Oxidation of such molybdenum species prior to the extraction step averts the formation of the emulsion ...

Structure and properties of molybdenum oxide nitrides as ...

Jul 15, 2011· Molybdenum oxide nitride (denoted as Mo(O,N) 3) was obtained by ammonolysis of α-MoO 3 with gaseous ammonia. Electronic and geometric structure, reducibility, and conductivity of Mo(O,N) 3 were investigated by XRD, XAS, UV-Vis spectroscopy, and impedance measurements. Catalytic performance in selective propene oxidation was determined by online mass spectrometry …

(PDF) Homogeneous liquid–liquid extraction method for the ...

Extraction of the ABO–molybdenyl complex, (C14 H12 O2 N2 )2 ·MoO2, from the acid medium is a selective method for the separation of molybdenum [1,18,19]. Thus, we examined ABO for the homogeneous liquid–liquid extraction of molybdenum.

Behavior of Extraction, Stripping, and Separation ...

the selective extraction of rhenium was obtained with low co-extraction of molybdenum at the equilibrium pH 0. 3.3 Possible extraction reaction mechanism The reaction mechanism of the protonation followed by extraction of Re and Mo with TOA …